爆炸冲击合成纳米碳化钛的研究

本文利用奥克托今炸药（HMX）作为高温、高压源，二氧化钛（TiO₂）和活性炭（C）作为前驱体，采用爆炸冲击合成的方法制备纳米碳化钛（TiC）粉末。运用X射线衍射分析仪(XRD)、X射线能谱分析仪(EDS) 及扫描电子显微镜(SEM) 对样品进行了分析与表征。探讨了爆炸冲击波作用下TiC的合成机理。结果表明:XRD和EDS测试值与理论值相符性很好，样品中同时含有TiC和TiC_x（x＜1）；SEM照片显示TiC和TiC_x（x＜1）的粒径均小于50 nm，样品中存在微米级的球形团聚体；爆炸冲击合成TiC属于特殊的固相反应，其物质扩散速度和反应速度大大提高。     

Water-mediated proton conduction in two stable fluorophenyl imidazole dicarboxylate-based cadmium(II) complexes

Transition Metal Chemistry - Recently, crystalline solid materials as proton conductors have attracted intensive attention. Herein, two highly stable complexes, 2D coordination polymer...     

基于字典学习的稠密光场重建算法

相机阵列是获取空间中目标光场信息的重要手段,采用大规模密集相机阵列获取高角度分辨率光场的方法增加了采样难度和设备成本,同时产生的大量数据的同步和传输需求也限制了光场采样规模.为了实现稀疏光场采样的稠密重建,本文基于稀疏光场数据,分析同一场景多视角图像的空间、角度信息的关联性和冗余性,建立有效的光场字典学习和稀疏编码数学模型,并根据稀疏编码元素间的约束关系,建立虚拟角度图像稀疏编码恢复模型,提出变换域稀疏编码恢复方法,并结合多场景稠密重建实验,验证提出方法的有效性.实验结果表明,本文方法能够对场景中的遮挡、阴影以及复杂的光影变化信息进行高质量恢复,可以用于复杂场景的稀疏光场稠密重建.本研究实现了线性采集稀疏光场的稠密重建,未来将针对非线性采集稀疏光场的稠密重建进行研究,以推进光场成像在实际工程中的应用.     

侧边抛磨的U型金溅射塑料光纤等离子体共振传感器

为了测量溶液折射率变化，对塑料光纤纤芯表面的纤芯-金层-液体的3层膜结构进行研究，制作了一种使用U型结构并结合侧边抛磨方法的表面等离子体共振传感器。将截取的一段塑料光纤弯曲成为U型，并在烘箱中通过较高温度使这段光纤的曲率固定，对弯曲部分的外表面进行抛光，暴露该位置塑料光纤芯层并在其上溅射金纳米薄膜层，将制备好的传感器浸入不同折射率的液体中，使用光谱分析仪观察光谱的移动。实验结果表明:当塑料光纤SPR传感器测量折射率变化范围在1.333~1.406的液体时，可以通过光谱观察到随着液体折射率的增大，等离子体共振吸收峰位置也不断地向波长增大的方向移动，并且二者之间存在线性关系，其灵敏度为7.5×10-4 RIU/nm。该传感器探头具有灵敏度高、小型化、易制备、低成本的特点。     

Impacts of climate change on vegetation pattern: Mathematical modeling and data analysis

Climate change has become increasingly severe, threatening ecosystem stability and, in particular, biodiversity. As a typical indicator of ecosystem evolution, vegetation growth is inevitably affected by climate change, and therefore has a great potential to provide valuable information for addressing such ecosystem problems. However, the impacts of climate change on vegetation growth, especially the spatial and temporal distribution of vegetation, are still lacking of comprehensive exposition. To this end, this review systematically reveals the influences of climate change on vegetation dynamics in both time and space by dynamical modeling the interactions of meteorological elements and vegetation growth. Moreover, we characterize the long-term evolution trend of vegetation growth under climate change in some typical regions based on data analysis. This work is expected to lay a necessary foundation for systematically revealing the coupling effect of climate change on the ecosystem.     

可变帧结构的PCM遥测帧同步器设计

针对传统帧同步器只能对固定帧格式的数据进行帧同步的缺点,提出一种基于现场可编程门阵列(FPGA)的帧同步方案,用户可根据实际需求通过上位机软件配置帧长、帧同步字等参数,实现对不同帧结构的PCM遥测数据进行帧同步。该方案采用了参数可调的同步容错及前后方保护机制,提高了帧同步的可靠性和稳定性。给出了帧同步方案的工作原理,以及关键技术的实现方法,在实际应用中对其同步性能进行分析,测试结果表明该方案对不同帧结构的数据均可实现帧同步。     

Investigation on the Percutaneous Enhancing Permeation Mechanism of Azone for Ketoprofen Based on the Intermolecular Hydrogen-bonding Interaction

The permeation enhancing activity of Azone for ketoprofen through excised cavia skins was investigated using Franz diffusion cell. The possible hydrogen-bonded complexes formed between ketoprofen and the model molecule of Azone as azacyclopentane-2-one were fully optimized at the B3LYP/6-311++G** level. The intermolecular hydrogen-bonding interactions were calculated using the B3LYP/6-311++G**, B3LYP/6-311++G(2df, 2p), MP2(full)/6-311++G** and MP2(full)/6-311++G(2df, 2p) methods, respectively. The results show that the steady-state permeation rate of ketoprofen through excised cavia skins enhances over 9 times in the solvent with 2% Azone as compared with the solvent without Azone. The stable O–H···O=C and N–H···O=C hydrogen-bonded complexes could exist between azacyclopentane and ketoprofen. The hydrogen-bonding interaction energy follows the order of(a) (b) (c) (d) (g)(e) (h) (f). The formation of the complexes leads to the change of the conformation and molecular polarity of ketoprofen, and thus causes a better percutaneous permeation for the drug. The analyses of AIM(atom in molecule) and shift of electron density were used to further reveal the nature of the enhancing permeation activity of Azone for ketoprofen. The investigations of the temperature and solvent effects confirm that ketoprofen might enter into the skin by means of the Azone complex.